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Electric Field-Dependent Charge-Carrier Velocity in Semiconducting Carbon Nanotubes

Electric Field-Dependent Charge-Carrier Velocity in Semiconducting Carbon Nanotubes

Yung-Fu Chen and M. S. Fuhrer Department of Physics and Center for Superconductivity Research, University of Maryland, College Park, MD 20742-4111, USA

Charge transport in semiconducting single-walled nanotubes (SWNTs) with Schottky-barrier contacts has been studied at high bias. We observe nearly symmetric ambipolar transport with electron and hole currents significantly exceeding 25 ?A, the reported current limit in metallic SWNTs due to optical phonon emission. Four simple models for the field-dependent velocity (ballistic, current saturation, velocity saturation, and constant mobility) are studied in the unipolar regime; the high-bias behavior is best explained by a velocity saturation model with a saturation velocity of 2 × 107 cm/s.

One of the most striking aspects of carbon nanotubes is that they can carry extremely large current densities [1-3], exceeding 109 A/cm2, orders of magnitude larger than those at which metal wires fail by electromigration [4]. Zone-boundary phonon emission at energy hf = 160 meV explains the current limit in metallic single-wall carbon nanotubes (SWNTs) of (4e/h)(hf) ≈ 25 ?A[1,5,6]. By using electrical breakdown of multi-wall carbon nanotubes (MWNTs), it was found that metallic and semiconducting shells carry similar saturation currents [2,7]. However, there is no reason to assume that the limit in semiconducting nanotubes is identical, since the electronic band structure is different: The equivalent zero-momentum phonon emission process in semiconducting nanotubes involves relaxation of electrons across the band gap. Bourlon, et al. proposed a model of competition between electron-phonon scattering and Zener tunneling to explain the geometrical dependence of saturation currents in metallic and semiconducting single shells in MWNTs [8], but experiments on single semiconducting SWNTs are lacking. In this letter we investigate high-bias transport in single Schottky-barrier (SB)contacted semiconducting SWNTs up to bias voltages of 10 V, corresponding to average electric fields up to 5 kV/cm. We examine four simple models for the electric-field dependence of the carrier velocity: ballistic, current saturation, velocity saturation, and constant mobility to understand the current at unipolar bias voltage regimes. The results are directly compared with the experimental data, and we find the best agreement with the velocity saturation model, with a saturation velocity vs of 2 × 107 cm/s. Heavily n-doped Si chips with a SiO2 layer of thickness t = 500 nm are used as our device substrates. SWNTs were grown using a chemical vapor deposition (CVD)

process with catalyst prepared as in Ref. 9 and carbon feedstock gases as introduced as in Ref. 10. A scanning electron microscope (SEM) was used to locate the nanotubes [11], and electron-beam lithography followed by thermal evaporation of 1.5 nm Cr and 100 nm Au formed the electrodes. Devices were annealed at 400 oC under Ar and H2 flow to lower the contact resistance. The diameters of the nanotubes were checked by atomic force microscope (AFM). We have investigated several semiconducting SWNT devices with similar transport behavior [12]. The measured nanotube diameters d range from 2 to 2.4 nm, and the nanotube lengths between the contacts (channel length L) range from 10 to 20 ?m. The measured nanotube diameters indicate they are SWNTs or small MWNTs. (We expect that in the case of a small MWNT with all semiconducting shells that the transport occurs primarily in the outermost shell with the lowest bandgap.) We focus on the transport data from one particular device, with d = 2.4 nm and L = 20 ?m. Electrical measurements were performed by grounding the source electrode (Vs = 0) and applying Vd to the drain, and Vg to the gate, while measuring the drain current Id. Figure 1 shows Id as a function of Vg at Vd = -1 V. This device behaves as an ambipolar semiconductor although p-type (hole) conduction is slightly better than n-type (electron) conduction. Because of the ambipolar behavior, we assume the presence of SBs at the electrodes for electrons and holes, but a smaller SB for holes. The maximum

transconductances gm for holes and electrons are ~ 2.5 and 2.0 ?A/V, respectively, which correspond to field-effect mobilities [13] ?FE ≈ 2.5 × 104 and 2.0 × 104 cm2/Vs (here we have used the electrostatic gate capacitance per length cg,e ≈ 2πεε 0 ln(4t d ) ≈ 0.2pF/cm where ε 0 is the electric constant, ε ≈ 2.45 the average dielectric constant of the oxide and

vacuum). The on-state conductances G ≈ 13 and 7 ?S for hole and electron indicate mean-free-paths l = LG/2G0 of at least 1.6 and 0.9 ?m. These values are comparable to the highest measured values for SWNTs [13] though contact resistance may play a significant role in this case. Figure 2 shows measured Id vs. Vd up to ±10 V at different gate biases Vg. We note several striking features of the data. First, the data is highly symmetric under reversal of both Vd and Vg, indicating ambipolar behavior. Second, the electron and hole currents significantly exceed 25 ?A with no obvious evidence of saturation. At finite positive (negative) gate voltages, the curves of Figure 2 show typical ntype (p-type) transistor behavior, i.e. saturation of Id at positive (negative) drain voltage. The saturation is followed by an increase in the current as Vd becomes greater than 2Vg. We interpret this increase in Id as the change from majority electron to majority hole current or vice versa. Vd = 2Vg corresponds to the symmetric bias condition [14,15], equivalent to holding Vg = 0 and applying equal and opposite voltages to source and drain; at this point electron and hole currents should be equal. The inset of Figure 2 shows the current is minimum at Vd = 2Vg. The curves for electrons and holes are similar, with slightly better conduction for holes, consistent with the low-bias data of Figure 1. We will focus here on the conduction at unipolar bias regions (Vg is larger than both Vd and Vs for electrons, or Vg is smaller than both Vd and Vs for holes). Under these bias conditions, there are very few minority carriers in the channel. (The ambipolar case, where the current contribution from minority carriers can not be ignored, will be discussed elsewhere.)

First we examine the expected behavior for a ballistic nanotube FET.


calculate the current using some assumptions and simplifications: (1) The nanotube is undoped. (2) The electrode Fermi level is aligned with the middle of the nanotube gap. (3) The subbands are approximated by a hyperbolic band

structure E (k ) ? (?e)VNT ( x) = m (hvF,m k ) 2 + (ν?) 2 , where the upper (lower) sign is for the valence (conduction) bands, VNT(x) is the potential of the nanotube at position x, k is the wave vector, vF,m = 9.35 × 105 m/s is the Fermi velocity of metallic nanotubes,
ν = 1 for first subbands, ν = 2 for second subbands, and ? is a half of nanotube bandgap.

(4) The device capacitance is dominated by capacitance to the gate since the channel length is fairly long compared with gate oxide thickness, and the charge density q ( x) = ± n( x)e = cg,e (VNT ( x) ? Vg ) is determined locally,

where n( x) = 4 ∫ dk ( f ( E (k > ) ? ? s ) + f ( E (k < ) ? ? d )) is the carrier density (the 4 from spin and subband degeneracies), k> (k<) means k is in the range of k > 0 (k < 0). (5) Zero temperature. (6) Contact resistance is neglected; i.e. the SBs at the contacts are

transparent once the bias across the SBs exceeds one-half the band gap. The last two assumptions are reasonable for describing transport at biases greatly exceeding the SB height and the temperature. VNT and n at the contacts are determined by satisfying the assumption (3), (4), (6) and bias conditions self-consistently. The current is then
1 ?E (k ) is h ?k

calculated by I = m4e ∫ d k ( f ( E (k > ) ? ? s ) + f ( E (k < ) ? ? d ))v(k ) , where v(k ) =

the velocity of state k. Here, only the lowest conduction bands or highest valence bands are considered to contribute the current conduction.

The result of the ballistic model for holes as majority carriers is plotted in Figure 4e 2 3(b). At low drain bias, the conductance is = 155 ?S, which is the signature of a h ballistic SWNT. At high positive drain bias, the current increases more slowly, with near-constant slope
cg,e cg,e 4e 2 ≈ 17 ?S, where cq = e2D(E) is the quantum capacitance, + cq h

with D(E) the energy-dependent density of states. Except for Fermi energies very near the band edge [16] cq is well approximated by the quantum capacitance of a metallic SWNT cq,m = 8e2/hvF,m ≈ 3.31 pF/cm. In the ballistic case, only the right-moving branch of the conduction band is filled, and cq = cq,m/2 ≈ 1.65 pF/cm. Here the hole density is limited by the voltage difference between gate and drain. At negative high drain bias, the current saturates because no more holes are added by increasing negative drain bias, since now the amount of holes is controlled by the voltage difference between gate and source. The ballistic model reproduces many of qualitative features of the experimental data in Figure 3(a), but the current and conductance are significantly higher than those in the experiment. This is reasonable: since the channel length is tens of microns, we do not expect ballistic transport. We next examine two models for the field-dependent velocity in the nanotube. In the first, the current saturation model, we assume that the maximum difference in the left- and right-moving quasi-Fermi levels is set by optical phonon scattering at hf ≈ 160 meV. The current is then limited to 4ef ≈ 25 ?A as observed in metallic nanotubes [1], and as has been suggested for semiconducting nanotubes [17]. The empirical I-V relation
V |V | = R0 + , where I0 = 25 ?A is the saturation current for I I0

metallic SWNT, was suggested in Ref. 1. If we represent this relation in terms of mobility ? and electric field E, we have:
? ?1 = ? 0 + ne

|E| , I0


where ?0 is the zero field mobility and n is the carrier density. Again using the assumptions above, we calculate the current I = q ( x) ?E ( x) , where E ( x) = ??VNT ( x) and q ( x) = cg,e (VNT ( x) ? Vg ) are functions of position x. The

result of the current saturation model for hole conduction is shown in Figure 3(c), where the fitting parameters are I0 = 25 ?A and zero field hole mobility ?0 = 2.7 × 104 cm2/Vs. (The zero-field mobility ?0, determined using the data in the range -0.1 V < Vd < 0.1 V, is slightly larger than the field effect mobility ?FE discussed above due to finite Vd = -1 V used there.) Figure 3(a) compares the calculation with experiment; disagreement is seen in several aspects. First, rather than saturating at 25 ?A at high positive drain bias, the measured current increases with roughly constant slope. Second, the current at negative bias is larger than that in experiment. I0 = 25 ?A was chosen assuming only the first valence subbands participate in the conduction and the physics is similar to metallic SWNT; however, no choice of I0 gives a good fit. Specifically, I0 = 50 ?A, which might correspond to two contributing subbands, is significantly worse. The qualitative agreement of the ballistic model with the measured current suggests that the charge-controlled model of the nanotube transistor, namely Id ∝ q, is correct. However, the charges must not move with Fermi velocity, but somewhat slower. In conventional semiconductors, typically the electric-field-dependent carrier velocity is

observed to saturate to a constant value at high electric field. Empirically, the carrier mobility often follows
? ?1 = ? 0 +

|E| , vs


where vs is the saturation velocity. Eq. (2) means at low E-field regime, the carrier velocity v increases linearly with E-field with slope ?0; at high E-field regime, v saturates at vs. Perebeinos, et al. have calculated electron-phonon interaction within a tight binding model and derive mobility-E-field relation for a single electron [18], and Eq. (2) fits their result very well. However, it is not at all clear whether their results extrapolated to many electrons would give current saturation or velocity saturation (since these are identical in a one-electron model). The calculation of current under the velocity saturation model is the same as that in the ballistic model except v = ?E, ? is described by Eq. (2), and the pinch-off effect is included [19]. The I-V curves of the velocity saturation model for hole conduction are plotted in Figure 3(d), where the fitting parameters are hole saturation velocity vs = 2 × 107 cm/s [20] and zero field hole mobility ?0 = 2.7 × 104 cm2/Vs. Simply speaking, ?0 is

determined by fitting the current at low drain bias; vs is determined by fitting the current at high negative drain bias. In order to compare the model, we plot in Figure 4 the saturation current Isat at different Vg for the experimental data and the current saturation and velocity saturation models. Also included is a calculation carried out for a constant hole mobility of 5000 cm2/Vs. The figure shows that the experimental behavior fits the velocity saturation model very well - the velocity saturation model predicts linear Isat vs. Vg, as seen in the

data. The current-saturation model always produces sublinear Isat vs. Vg, while the constant mobility model has Isat ~ Vg2. Though a simple model of velocity saturation describes the experimental data surprisingly well, some problems remain. First, contact effects are not considered, which causes poor agreement around Vd = 0 and Vg = 0. Second, the experimental current at high positive drain bias does not increase as fast as expected, indicating that vs may decrease slightly with increasing charge density. understand SWNT transistors under high-bias voltages. The saturation velocity is smaller than the peak carrier velocity of 4.5 × 107 cm/s in Ref. 21 for a 2.4 nm diameter nanotube at an electric field of ~ 5 kV/cm, and 5 × 107 cm/s in Ref. 18 using a one-electron model, but is still more than twice as high as in silicon inversion layers [22]. The authors are grateful for support from the National Science Foundation under grant DMR-01-02950, and for useful discussions with Gary Pennington, Akin Akturk, and Neil Goldsman. More study is needed to fully

References: [1] Z. Yao, C. L. Kane, and C. Dekker, Physical Review Letters 84, 2941 (2000). [2] P. C. Collins, M. S. Arnold, and P. Avouris, Science 292, 706 (2001). [3] B. Q. Wei, R. Vajtai, and P. M. Ajayan, Applied Physics Letters 79, 1172 (2001). [4] D. Young and A. Christou, Ieee Transactions on Reliability 43, 186 (1994). [5] J. Y. Park, et al., Nano Letters 4, 517 (2004). [6] A. Javey, et al., Physical Review Letters 92, 106804 (2004). [7] P. G. Collins, et al., Physical Review Letters 86, 3128 (2001). [8] B. Bourlon, et al., Physical Review Letters 92, 026804 (2004). [9] J. H. Hafner, et al., Journal of Physical Chemistry B 105, 743 (2001). [10] W. Kim, et al., Nano Letters 2, 703 (2002). [11] T. Brintlinger, et al., Applied Physics Letters 81, 2454 (2002). [12] Some devices showed only unipolar p-type behavior; we associate these devices with Ohmically-contacted nanotubes. Only the ambipolar devices, which we assume to be Schottky-barrier transistors, are discussed in this letter. [13] T. Durkop, et al., Nano Letters 4, 35 (2004). [14] J. A. Misewich, et al., Science 300, 783 (2003). [15] M. Radosavljevic, et al., Applied Physics Letters 83, 2435 (2003). [16] S. Rosenblatt, et al., Nano Letters 2, 869 (2002). [17] A. Javey, et al., Nature 424, 654 (2003). [18] V. Perebeinos, J. Tersoff, and P. Avouris, Physical Review Letters 94, 086802 (2005).

[19] Pinch-off happens because the carrier velocity is limited at vs. To maintain constant current in nanotube, the channel needs finite amount of charge even when Vd approaches Vg. We include the pinch-off effect in velocity saturation model as follows: when we calculate Id vs. negative Vd, the magnitude of current eventually starts to decrease as Vd is beyond a threshold voltage Vd,th; i.e. the maximum of Id, Id,max, occurs at Vd,th. The current is fixed at Id,max when Vd is greater than Vd,th. The same procedure is applied to the source when Vd is positive. [20] The unipolar majority-electron bias region (Vg larger than both Vd and Vs) is very similar to the majority-hole region, indicating symmetric conduction and valence band structure. By a similar analysis, we find the electron saturation velocity is also ~ 2 × 107 cm/s. [21] G. Pennington and N. Goldsman, Physical Review B 68, 045426 (2003). [22] J. A. Cooper and D. F. Nelson, Journal of Applied Physics 54, 1445 (1983).

Figure Captions: Figure 1. Drain current Id as a function of gate voltage Vg at drain voltage Vd = -1 V and temperature 4.2 K. The solid and dashed lines correspond to linear (left) and logarithmic (right) scales, respectively.

Figure 2. Ambipolar semiconducting nanotube transistor.

(a) Drain current Id as a

function of drain voltage Vd at gate voltages Vg from -9 V to 9 V, in 1 V steps is measured. Vd is applied up to ±10 V. Temperature is 4.2 K. The inset is a color-scale plot of Id as a function of Vd and Vg, where red and blue colors represent positive and negative Id, respectively. The dashed line in the inset indicates Vg = Vd/2; the current minimum occurs along this line.

Figure 3. Comparison between experimental data and simulation for several models with holes as majority carriers. (a) Experimental Id as a function of Vd at Vg from -9 V to -1 V, in 1 V steps. The thick curve is for Vg = -9 V. (b) Ballistic model (c) current saturation model, and (d) velocity saturation model are plotted for the same gate voltages as the experimental data. Note the different vertical scale for (b).

Figure 4. Saturation current Isat at different Vg for experimental data and theoretical models discussed in text. Isat is Id at Vd = Vg.

Figure 1
15 Vd = -1 V 10
-Id ( ?A)





-Id ( ?A)


hole -10 -5 0 V g (V) 5

electron 0.01 10

Figure 2
30 20
5 0 -5 -5 0 5 Vg (V) V d (V) -20 0 20 Id (?A)

Id (?A)

10 0 -10 -20 -30 -10

Vg = -9 V Vg = 0 V Vg = 9 V





Vd (V)

Figure 3

20 0 -20 200


100 0

Id (?A)


20 0 -20 20 0 -20 -10







Vd (V)

Figure 4
-25 -20
exp current saturation velocity saturation constant mobility

Isat (?A)

-15 -10 -5 0







Vg (V)

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